Re: Fluorochromes choice

From: Richard Haugland (richard.haugland@probes.com)
Date: Mon Nov 04 2002 - 19:48:59 EST


I'm sorry for the post that offended some people as "advertising."  It
was specifically intended to go directly to only the questioner but
inadvertently went to "all". I usually try to post to the Board only
those responses that I feel will be of general interest and are, in most
cases, a solution or information that others are unlikely to give but
make many other responses directly only to the individual.

With regards the matter of 325-nm light-excitable dyes, Bill is right
that there are few dyes useful for conjugation in this spectral region.

Alexa Fluor 350 (AMCA has absorption and emission peaks about 8 nm
longer than Alexa Fluor 350).

[Spectra: 12KB]

and Cascade Blue

[Spectra: 12KB]



These are normalized spectra and the extinction at 325 nm for each dye
is perhaps 6000-8000 because Cascade Blue has a higher peak extinction.

Pacific Blue is really quite long wavelength for the 325-nm laser and
has emission stretching more into the >500 nm spectral range.

[Spectra: 12KB]



It is probable that 7-methoxycoumarin-3-carboxylic acid would make a
good fluorophore (exc max ~336 nm, em max ~402 nm) with an extinction at
336 nm of about 20,000 but we have never seen an interest in this
spectral range previously. 7-methoxycoumarin-4-acetic acid may be an
even better match but I don't have those data. It is sometimes used as
the fluorophore in quenched protease substrates.


William Telford wrote:

> Hello Michal...
>
> Although I agree with almost all the comments so far about doing
> 6-color on the original LSR, you still might want to give the
> UV-excited fluorochrome AMCA (or its more recent descendant Alexa
> Fluor 350) a try as your sixth color.  AMCA is actually a reasonably
> bright fluorochrome - unfortunately its emission at ~450 nm falls in
> an area of high cellular autofluorescence, making it appear dim
> relative to background.  However, if you use it to label a densely
> expressed marker, it might be bright enough to visualize.  We've made
> it work in the past for a few highly expressed surface markers, such
> as CD8 on mouse T cells - expect at least a one-to two log decrease in
> fluorescence compared to FITC.  Use your 424/44 filter for detection.
> We have also tried AMCA and Alexa Fluor 350 with a variety of UV
> lasers - although its emission peak is around 350 nm, the HeCad 325 nm
> line still seems to excite it as well as (or no worse than, anyway)
> the longer argon and krypton UV lines.  You can use Alexa Fluor
> 350-streptavidin to label a biotin-conjugated antibody, or use the
> Zenon kit from MPI to make a "conjugate".
>
> From an instrument standpoint, you might want to get the 4-2-2 LSR
> upgrade to do four colors off the 488 nm and two off the 633 nm.  I
> know this configuration exists for the LSR, although I'm not
> absolutely sure if BD is routinely doing upgrades to it.  Alternately,
> you might want to consider investing in the 405 nm violet laser diode
> upgrade and use Cascade or Pacific Blue as your sixth colors, which
> give much better signal-to-noise ratios than AMCA.
>
> Enjoy,
>
> Bill Telford
> NCI-NIH
>
> (and yes, no financial stake in Molecular Probes, BD Bioscience, or
> anyone else for that matter!)
>
> At 11:21 AM 10/30/2002 -0800, Michal Abel wrote:
>
>
>> Dear experts in flow cytometry,
>>
>> I have a possibility to use 6 colors FACS. The trouble is that I am
>> not sure it is possible with the filters I have.
>> I would very much appreciate any help.
>> The instrument has three lasers: 325, 488 and 633 nm and I can use
>> following filters:
>> 380/LP
>> 400/40
>> 424/44
>> 500/11
>> 510/20
>> 530/28
>> 575/15
>> 610/20
>> 660/13
>> 670/LP
>> 682/13
>> Is it possible to find 6 different flourochromes, which would be
>> efficiently differentiated with these filters/lasers ?
>>
>> Thank you very much for your help.
>>
>> Michal
>>
>>
>> --
>>
>> Michal Abel, MD, PhD
>> Laboratory of Clinical Immunology
>> INSERM U25
>> Necker Hospital, 161 Rue de Sèvres. Paris
>> tel: 33 1 42 19 28 87
>> fax: 33 1 44 49 53 74
>



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