Re: para/formaldehyde & minimacs

From: Carol.W.Johnson@ap.pnu.com
Date: Tue Aug 15 2000 - 09:25:57 EST


To fellow flowers,

As a veterinary pathologist who works with both formalin and paraformaldehyde
solutions, I felt that Dr. Zbigniew Darzynkiewicz' answer gave some of the most
practical information.  The formaldehyde (dissolved gas) in formalin solution or
made from 37% 'formaldehyde solution' can be extensively polymerized while the
formaldehyde (dissolved gas) made from a fresh paraformaldehyde solution is
largely monomeric.  In addition, in formalin or formaldehyde solutions,
breakdown and rearrangment products from the formaldehyde gas form
gluteraldehyde and other adehydes spontaneously.   As noted, most formalin
solutions also contain methanol.

>From a practical aspect, it means that formalin and 'formaldehyde' solutions
will destroy some antigens that a fresh paraformaldehyde solution might
preserve.

The formaldehyde in paraformaldehyde solutions will also undergo spontaneous
polymerization and breakdown with time and therefore, from a practical aspect,
may not preserve the test antigen with time.   For some of the antigens that we
work with, paraformaldehyde solution is useful for days to about a week after it
is made and after that, the antigen is not preserved to the same extent as a
fresh solution.  Other antigens are not labile and can be fixed even in formalin
or aged paraformadehyde (or alchohols for that matter).

Anyone using paraformaldehyde solutions should be aware of these issues and work
out the optimal conditions for their particular antigens.

Carol W. Johnson, DVM PhD
Pharmacia Corp.
Kalamazoo MI



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