Re: UV (280 nm) excitation in flow for lanthanides?

From: Howard Shapiro (hms@shapirolab.com)
Date: Fri Apr 14 2000 - 17:13:53 EST


Dane Wittrup writes:


>Does anybody have their flow instrument set up for excitation from 280-300
>nm?  We'd like to excite a lanthanide bound in calmodulin, using Trp as the
>donor to the ion.

There aren't a lot of people who have lasers that will do those deep UV
lines - the only publication in this area which comes to mind was from the
Jovins in Goettingen in the late 1970's, looking at Trp fluorescence in
proteins.

However, if you're really interested and have the laser (which would
presumably be on an optical bench) and optical filters, I could bring over
the rest of a cytometer.  You might also be able to scrounge the
do-it-yourself cytometer parts from Penny Chisholm's lab, which is even
closer to you.

Of course, the real problem might be the lanthanide lifetime; as I recall,
this runs into many microseconds, while the typical dwell time in the beam
of a cytometer is only a few microseconds.  Call if you're interested
(617-783-8392 or 617-965-6044).

-Howard



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